The Effect of Wavelength on Photovoltaic Cells
Solar cells depend on a phenomenon known as the photovoltaic effect, discovered by French physicist Alexandre Edmond Becquerel (1820-1891). It is related to the photoelectric effect, a phenomenon by which electrons are ejected from a conducting material when light shines on it.
Albert Einstein (1879-1955) won the 1921 Nobel Prize in physics for his explanation of that phenomenon, using quantum principles that were new at the time. Unlike the photoelectric effect, the photovoltaic effect takes place at the boundary of two semiconducting plates, not on a single conducting plate. No electrons are actually ejected when light shines. Instead, they accumulate along the boundary to create a voltage. When you connect the two plates with a conducting wire, a current will flow in the wire.
Einstein's great achievement, and the reason for which he won the Nobel Prize, was to recognize that the energy of the electrons ejected from a photoelectric plate depended – not on light intensity (amplitude), as wave theory predicted – but on frequency, which is the inverse of wavelength.The shorter the wavelength of incident light, the higher the frequency of the light and the more energy possessed by ejected electrons. In the same way, photovoltaic cells are sensitive to wavelength and respond better to sunlight in some parts of the spectrum than others. To understand why, it helps to review Einstein's explanation of the photoelectric effect.
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Sunlight contains an entire spectrum of radiation, but only light with a short enough wavelength will produce the photoelectric or photovoltaic effects. This means that a part of the solar spectrum is useful for generating electricity. It doesn't matter how bright or dim the light is. It just has to have – at a minimum – the solar cell wavelength. High-energy ultraviolet radiation can penetrate clouds, which means that solar cells should function on cloudy days – and they do.